A light-emitting diode, usually called an LED (pronounced /ˌɛliːˈdiː/),[1] is a semiconductor diode that emits incoherent narrow-spectrum light when electrically biased in the forward direction of the p-n junction, as in the common LED circuit. This effect is a form of electroluminescence.
Discovery and development
The first known report of a light-emitting solid-state diode was made in 1907 by the British experimenter H. J. Round of Marconi Labs. Russian Oleg Vladimirovich Losev independently created the first LED in the mid 1920s; his research, though distributed in Russian, German and British scientific journals, was ignored, [5] [6] and no practical use was made of the discovery for several decades. Rubin Braunstein of the Radio Corporation of America reported on infrared emission from gallium arsenide (GaAs) and other semiconductor alloys in 1955. [7] . Braunstein observed infrared emission generated by simple diode structures using GaSb, GaAs, InP, and Ge-Si alloys cooled by liquid nitrogen to 77 K. Experimenters at Texas Instruments, Bob Biard [8] and Gary Pittman, found in 1961 that gallium arsenide gave off infrared radiation when electric current was applied. Biard and Pittman were able to establish the priority of their work and received the patent for the infrared light-emitting diode.
Practical use
The first commercial LEDs were commonly used as replacements for incandescent indicators, and in seven-segment displays, first in expensive equipment such as laboratory and electronics test equipment, then later in such appliances as TVs, radios, telephones, calculators, and even watches. These red LEDs were bright enough only for use as indicators, as the light output was not enough to illuminate an area. Later, other colors became widely available and also appeared in appliances and equipment. As the LED materials technology became more advanced, the light output was increased, while maintaining the efficiency and the reliability to an acceptable level, causing LEDs to become bright enough to be used for illumination.
Physical principles
I-V diagram for a diode an LED will begin to emit light when the on-voltage is exceeded. Typical on voltages are 2-3 Volt
Like a normal diode, the LED consists of a chip of semiconducting material impregnated, or doped, with impurities to create a p-n junction. As in other diodes, current flows easily from the p-side, or anode, to the n-side, or cathode, but not in the reverse direction. Charge-carriers—electrons and holes—flow into the junction from electrodes with different voltages. When an electron meets a hole, it falls into a lower energy level, and releases energy in the form of a photon.
The wavelength of the light emitted, and therefore its color, depends on the band gap energy of the materials forming the p-n junction. In silicon or germanium diodes, the electrons and holes recombine by a non-radiative transition which produces no optical emission, because these are indirect band gap materials. The materials used for the LED have a direct band gap with energies corresponding to near-infrared, visible or near-ultraviolet light.
LED development began with infrared and red devices made with gallium arsenide. Advances in materials science have made possible the production of devices with ever-shorter wavelengths, producing light in a variety of colors.
LEDs are usually built on an n-type substrate, with an electrode attached to the p-type layer deposited on its surface. P-type substrates, while less common, occur as well. Many commercial LEDs, especially GaN/InGaN, also use sapphire substrate.
Ultraviolet and blue LEDs
Ultraviolet GaN LEDs.
Blue LEDs are based on the wide band gap semiconductors GaN (gallium nitride) and InGaN (indium gallium nitride). They can be added to existing red and green LEDs to produce the impression of white light, though white LEDs today rarely use this principle.
The first blue LEDs were made in 1971 by Jacques Pankove (inventor of the gallium nitride LED) at RCA Laboratories.[17] However, these devices had too little light output to be of much practical use. In the late 1980s, key breakthroughs in GaN epitaxial growth and p-type doping by Isamu Akasaki and Hiroshi Amano (Nagoya, Japan)[18] ushered in the modern era of GaN-based optoelectronic devices. Building upon this foundation, in 1993 high brightness blue LEDs were demonstrated through the work of Shuji Nakamura at Nichia Corporation.[19]
By the late 1990s, blue LEDs had become widely available. They have an active region consisting of one or more InGaN quantum wells sandwiched between thicker layers of GaN, called cladding layers. By varying the relative InN-GaN fraction in the InGaN quantum wells, the light emission can be varied from violet to amber. AlGaN aluminium gallium nitride of varying AlN fraction can be used to manufacture the cladding and quantum well layers for ultraviolet LEDs, but these devices have not yet reached the level of efficiency and technological maturity of the InGaN-GaN blue/green devices. If the active quantum well layers are GaN, as opposed to alloyed InGaN or AlGaN, the device will emit near-ultraviolet light with wavelengths around 350–370 nm. Green LEDs manufactured from the InGaN-GaN system are far more efficient and brighter than green LEDs produced with non-nitride material systems.
Considerations in use
Close-up of a typical LED in its case, showing the internal structure.
Unlike incandescent light bulbs, which light up regardless of the electrical polarity, LEDs will only light with correct electrical polarity. When the voltage across the p-n junction is in the correct direction, a significant current flows and the device is said to be forward-biased. If the voltage is of the wrong polarity, the device is said to be reverse biased, very little current flows, and no light is emitted. LEDs can be operated on an alternating current voltage, but they will only light with positive voltage, causing the LED to turn on and off at the frequency of the AC supply.
While the only definitive way to determine the polarity of the LED is to examine its datasheet, these methods are usually reliable:
sign:
+
-
terminal:
anode (A)
cathode (K)
leads:
long
short
exterior:
round
flat
interior:
small
large
wiring:
red
black
Less reliable methods of determining polarity are:
sign:
+
-
marking:
none
stripe
pin:
1
2
PCB:
round
square
While it is not an officially reliable method, it is almost universally true that the cup that holds the LED die corresponds to the cathode. It is strongly recommended to apply a safe voltage and observe the illumination as a test regardless of what method is used to determine the polarity.
Because the voltage versus current characteristics of the LED are much like any diode (that is, current approximately an exponential function of voltage), a small voltage change results in a huge change in current. Added to deviations in the process this means that a voltage source may barely make one LED light while taking another of the same type beyond its maximum ratings and potentially destroying it.
Since the voltage is logarithmically related to the current it can be considered to remain largely constant over the LED's operating range. Thus the power can be considered to be essentially proportional to the current. In order to keep power nearly constant with variations in supply and LED characteristics, the power supply should be a “current source”, that is, it should supply an almost constant current. If high efficiency is not required (e.g., in most indicator applications), an approximation to a current source is made by connecting the LED in series with a current limiting resistor to a regulated voltage source.
Most LEDs have low reverse breakdown voltage ratings, so they will also be damaged by an applied reverse voltage of more than a few volts. Since some manufacturers don't follow the indicator standards above, if possible the data sheet should be consulted before hooking up the LED, or the LED may be tested in series with a resistor on a sufficiently low voltage supply to avoid the reverse breakdown. If it is desired to drive the LED directly from an AC supply of more than the reverse breakdown voltage then it may be protected by placing a diode (or another LED) in inverse parallel.
LEDs can be purchased with built in series resistors. These can save PCB space and are especially useful when building prototypes or populating a PCB in a way other than its designers intended. However, the resistor value is set at the time of manufacture, removing one of the key methods of setting the LED's intensity. To increase efficiency (or to allow intensity control without the complexity of a DAC), the power may be applied periodically or intermittently; so long as the flicker rate is greater than the human flicker fusion threshold, the LED will appear to be continuously lit.
Multiple LEDs can be connected in series with a single current limiting resistor provided the source voltage is greater than the sum of the individual LED threshold voltages. Parallel operation is also possible but can be more problematic. Parallel LEDs must have closely matched forward voltages (Vf) in order to have equal branch currents and, therefore, equal light output. Variations in the manufacturing process can make it difficult to obtain satisfactory operation when connecting some types of LEDs in parallel.[27]
Bicolor LED units contain two diodes, one in each direction (that is, two diodes in inverse parallel) and each a different color (typically red and green), allowing two-color operation or a range of apparent colors to be created by altering the percentage of time the voltage is in each polarity. Other LED units contain two or more diodes (of different colors) arranged in either a common anode or common cathode configuration. These can be driven to different colors without reversing the polarity, however, more than two electrodes (leads) are required.
LEDs are usually constantly illuminated when a current passes through them, but flashing LEDs are also available. Flashing LEDs resemble standard LEDs but they contain an integrated multivibrator circuit inside which causes the LED to flash with a typical period of one second. This type of LED comes most commonly as red, yellow, or green. Most flashing LEDs emit light of a single wavelength, but multicolored flashing LEDs are available too.
Generally, for newer common standard LEDs in 3 mm or 5 mm packages, the following forward DC potential differences are typically measured. The forward potential difference depending on the LED's chemistry, temperature, and on the current (values here are for approx. 20 mA, a commonly-found maximum value).
Color
Potential Difference (Vf)
Infrared
1.6 V
Red
1.8–2.1 V
Orange
2.2 V
Yellow
2.4 V
Green
2.6 V
Blue
3.0–3.5 V
White
3.0–3.5 V
Ultraviolet
3.5 V
Many LEDs are rated at 3 V maximum reverse potential.